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Semester 1 Review - AP Chemistry
Semester 1 Review - AP Chemistry
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Review for the AP Chemistry midterm exam
Flashcards
75 cards
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Practice quiz
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Questions
75
Answers
1
Of the following, the smallest and lightest subatomic particle is
Electron
Protons
Neutron
Alpha particle
2
A solution with a concentration higher than the solubility is
Supersaturated
Not possible
Saturated
Unsaturated
3
When four atomic orbitals are mixed, how many hybrid orbitals are formed?
One
Four
Five
Six
4
Which will effuse through a hole most quickly?
C3H8 gas
C2H2 gas
C2H6 gas
CH4 gas
5
An antibonding MO ___ the corresponding bonding MO.
Is always lower in energy than
Is always degenerate with
Can accommodate more electrons than
Is always higher in energy than
6
Of the choices, which is not an ionic compound?
PbCl2
MoCl6
PCl5
NaCl
7
In some molecules, the sum of valence electrons is odd and the octet rule fails.
True
False
8
Which of the following is a weak electrolyte?
LiBr
HNO3
C2H5OH
NH3
9
The point in a titration at which the indicator changes is called the _____.
Standard point
Indicator point
Volumetric point
End point
10
As concentration of solute increases, freezing point ___ and vapor pressure ___.
Increases, increases
Decreases, decreases
Decreases, increases
Increases, decreases
11
In order to exhibit delocalized π bonding, a molecule must have
At least two π bonds
At least two resonance structures
At least four atoms
At least three sigma bonds
12
Which one of the following basic forces is so small that it has no chemical significance?
Electromagnetism
Weak nuclear force
Gravity
Strong nuclear force
13
Of the following substances, ___ has the highest boiling point.
Br2
O2
N2
Cl2
14
The oxidation number of oxygen in H
2
O is _____.
-1
+2
-2
+1
15
The area labeled ___ on the following phase diagram represents the gas phase.
w and x
w
x
y
16
Which of the following is soluble in water?
Hg2Cl2
PbCl2
AgNO3
Ag2S
17
Bromine is more apt to exist as an anion than is potassium. This is because
Bromine is bigger than potassium
Bromine has a greater ionization energy than potassium does
Bromine is a liquid and potassium is a solid
Bromine has a greater electron affinity than potassium does
18
When argon is placed in a container of neon, it spontaneously disperses because
Solvent-solute interactions
A decrease in energy occurs when the two mix
The dispersion of argon produces an increase in disorder
Hydrogen bonding
19
Which of the following is not a strong electrolyte?
MgCl2
KCl
HCl
HC2H3O2
20
Electrons in the ___ subshell experience the lowest effective nuclear charge in an atom.
3p
5s
5p
1s
21
Which pair of elements would you expect to exhibit the greatest similarity in properties?
Ga, Ge
Cs, Ba
Ca, Sr
C, O
22
A strong electrolyte is one that _____ completely in solution.
Reacts
Associates
Disappears
Ionizes
23
Of the atoms below, ___ is the most electronegative.
Ca
Mg
Ba
Be
24
Which hydroxide is not a strong base?
Sr(OH)2
NaOH
KOH
All of these are strong bases
25
Of the following, only ____ has dispersion forces as the only intermolecular force.
Kr
HCl
CH3OH
NH3
26
In which of these is hydrogen bonding the most significant part of total intermolecular forces?
CH4
C5H11OH
CH3OH
C6H13NH2
27
A weak electrolyte exists predominantly as _____ in solution.
Ions
Electrons
Molecules
Atoms
28
Of the molecules below, the bond in ____ is the most polar
HF
HI
H2
HBr
29
The shape of a liquid's meniscus is determined by
The volume of the liquid
The viscosity of the liquid
The amounts of cohesion and adhesion
The type of material the container is made of
30
In a hydrogen atom, an electron in a ____ orbital can absorb a photon, but cannot emit a photon
1s
3f
3p
2s
31
The region of the following phase diagram that corresponds to the solid phase is
w
x
y
x and y
32
Of the following, ___ should have the highest critical temperature.
CH4
CF4
CBr4
CCl4
33
Oxidation is the _____ and reduction is the _____.
Gain of electrons, loss of electrons
Gain of oxygen, loss of electrons
Loss of oxygen, gain of electrons
Loss of electrons, gain of electrons
34
______ have the lowest first ionization energies of the groups listed.
Alkali metals
Alkaline earth metals
Noble gases
Transition metals
35
Which of the following is not a strong acid?
HBr
HI
HNO3
HF
36
Homogeneous mixtures are also known as
Compounds
Substances
Elements
Solutions
37
Of the following, _____ is the most volatile.
C2H6
C2F6
C2Br6
C2Cl6
38
Atomic radius generally increases as we move
Up a group and from right to left across a period
Up a group and from left to right across a period
Down a group and from left to right across a period
Down a group and from right to left across a period
39
A typical triple bond
Consists of three shared electrons
Consists of one sigma bond and two pi bond
Consists of two sigma bonds and one pi bond
Is longer than a single bond
40
The critical temperature is
The temperature at which all three states are in equilibrium
The temperature below which a gas cannot be liquefied
The temperature required to cause sublimation of a solid
The temperature above which a gas cannot be liquefied
41
There are ___ orbitals in the third shell.
18
9
1
16
42
The ____ orbital is degenerate with 5p
y
in a many-electron atom.
4py
5dxy
5s
5px
43
Which of the following is an illustration of the law of constant composition?
Water is a compound
Water and salt have different boiling points
Water is 11% hydrogen and 89% oxygen by mass
Water boils at 100°C at 1 atm pressure
44
For resonance forms of a molecule or ion,
There cannot be more than two resonance structure
All resonance structures are observed in various proportions
The observed structure is an average of the resonance forms
One always corresponds to the observed structure
45
The principal quantum number of the first d subshell is
1
2
4
3
46
Which ion has the largest radius?
Br-
Na+
K+
F-
47
Which of the following is insoluble in water?
Na2S
Mg3(PO4)2
Ca(OH)2
(NH4)2CO3
48
Which will diffuse through a room most quickly?
Ar
Ne
Kr
He
49
Energy is ______ proportional to frequency and ______ proportional to wavelength.
Directly, directly
Directly, inversely
Inversely, inversely
Inversely, directly
50
Which one of the following is more likely to dissolve in benzene (C
6
H
6
)?
HBr
CCl4
CH3CH2OH
NaCl
51
Of the species below, only _____ is not an electrolyte.
HCl
KOH
NaCl
Ar
52
Viscosity increases as intermolecular forces increase.
True
False
53
The force of attraction between Na
+
and H
2
O in dissolved NaCl is called a(n) _____ interaction.
Ion-dipole
Hydrogen bonding
Dipole-dipole
London dispersion
54
According to MO theory, overlap of two s atomic orbitals produces
One bonding and one antibonding molecular orbital
Two bonding molecular orbitals
Two bonding and two antibonding molecular orbtials
Two bonding and one antibonding molecular orbitals
55
A small amount of salt dissolved in water is an example of a
Homogeneous mixture
Compound
Pure substance
Heterogeneous mixture
56
Which of the following is a diprotic acid?
Phosphoric acid
Nitric acid
Sulfuric acid
Chloric acid
57
Which one of the following molecular formulas is also an empirical formula?
C2H6SO
H2O2
C6H6
H2P4O6
58
In which of the following numbers are none of the zeros significant?
161.00
103
0.00050
0.009
59
A molecular orbital can accommodate a maximum of ___ electrons.
6
2
1
4
60
A separation process that depends on differing abilities of substances to form gases is called
Chromatography
Distillation
Filtration
Solvation
61
When a metal and a nonmetal react, the ______ loses electrons and the ______ gains electrons.
Metal, nonmetal
Nonmetal, metal
Nonmetal, nonmetal
Metal, metal
62
An atom of
197
Au, has ____ protons, ____ neutrons, and ____ electrons.
197, 79, 118
79, 197, 197
79, 118, 118
79, 118, 79
63
Oxidation cannot occur without _____.
Air
Acid
Reduction
Oxygen
64
For which of the following can the composition vary?
Element
Both homogeneous and heterogeneous mixtures
Pure substance
Heterogeneous mixture
65
Which statement is false?
Substances with similar intermolecular forces are miscible
Solubility of gases in water decreases with increasing temp.
Solubility of a gas increases with increased pressure
Weaker attraction between solute & solvent = More solubility
66
The vapor pressure of any substance at its normal boiling point is
1 atm
Equal to atmospheric pressure
Equal to the vapor pressure of water
1 torr
67
If matter is uniform throughout and can be separated by chemical but not physical processes
It is a homogeneous mixture
It is a compound
It is a mixture of elements
It is an element
68
Cathode rays are deflected away from a negatively charged plate becasue
They are emitted by all matter
They are negatively charged particles
They are positively charged particles
They are neutral particles
69
Which one of the following will occur as diatomic molecules in elemental form?
Argon
Helium
Chlorine
Phosphorus
70
Viscosity increases as temperature increases
False
True
71
The oxidation number of oxygen in H
2
O
2
is _____.
-2
-1
+1
+2
72
The ___ subshell contains only one orbital.
3d
5p
4s
1p
73
Viscosity increases as molecular weight increases.
False
True
74
Each p subshell can accommodate a maximum of ___ electrons.
2
6
3
5
75
In ionic bond formation, the lattice energy of ions ___ as the charges ___ and the radii ___.
Increases, increase, increase
Increases, increase, decrease
Decreases, increase, increase
Increases, decrease, decrease